Sustainability of thermal energy production at the flooded mine workings of the former Caphouse Colliery, Yorkshire, United Kingdom

Abandoned, flooded, coal mine workings are an artefact of fossil fuel exploitation that can be repurposed as a renewable energy resource. The warm subsurface waters that fill former workings can be developed to provide efficient and low-carbon heat generation using ground source heat pumps. In order to determine the long-term suitability of flooded mine workings as a sustainable thermal resource we have to understand the hydrological components of the system and how they interact in response to exploitation-related disturbance. We investigate pump induced mixing dynamics at the former Caphouse Colliery, which has been pumped since 1996 for regional water level management but only recently started to be explored as a thermal resource. Initial findings from the first 6 months of study show virtually no variation in physiochemical, major ion or stable isotope values. However, placed in context with archived values from 2004 to the present, we see a general pattern of mine water quality recovery punctuated by a doubling of Cl− values (150 mg/l to > 300 mg/l) which may suggest recent ingress of deeper-sourced saline waters. This is supported by O and H isotopic values, which are indicative of ancient, perhaps Late Pleistocene, confined waters. Sulphur isotope values (19.7–23.8‰) are abnormally high as compared to typical values for Carboniferous Coal Measures (0–10‰). There is no simple explanation, so further data collection and investigation are required, though we note that these values are similar to Lower Carboniferous seawater values. The relative stability of recent parameters suggests that Caphouse waters represent a dependable thermal resource. However, much about the hydrogeology of the Caphouse system is still uncertain, so further work is required to check the persistence of recent trends

U-Th dating of travertines on the Colorado Plateau: implications for the leakage of geologically stored CO2

In order to avoid the damaging climatic consequences of rising atmospheric CO2, and reduce current atmospheric CO2 concentrations to pre-industrial levels, anthropogenic CO2 emissions must be mitigated by capturing CO2 at power plants and storing it for thousands of years. Underground storage within deep geological formations, such as depleted gas and oil fields or deep saline aquifers, is the best understood solution for storage of CO2. In order for this method to gain more public and political acceptance it is important to characterise the potential causes, quantities and rates of CO2 release that could result if leakage were to occur from anthropogenic storage projects. This study examines two sites in the Colorado Plateau where faulted and actively leaking CO2 reservoirs provide natural analogues for failed anthropogenic storage sites. The two sites in question, the Little Grand Wash and northern Salt Wash graben faults are situated at the northern end of the Paradox Basin in Utah and represent classic three way traps due to juxtaposition of the shallow, north plunging Green River anticline against a set of east-west trending normal faults. In addition to active leakage sites in each area there are numerous fossilised travertine deposits. Along the Little Grand Wash fault the ancient mounds are restricted to the fault trace whereas ancient travertine mounds associated with the northern fault of the Salt Wash graben are far more numerous and occur up to ~530 m into the footwall of the fault. This more diffuse pattern of flow is due to the outcropping of unconfined aquifer units at the surface. A total of 45 U-Th dates from the majority of these travertine mounds provides a unique data set. The oldest deposits from the Little Grand Wash and northern Salt Wash graben faults produced ages of 113,912 ± 604 and 413,474 ± 15,127 years respectively. Repeat ages show reasonable reproducibility and analytical errors on results are of the order of 1% of the ages. The coupling of travertine elevation measurements with their radiometric ages gives an incision rate for each site. A rate of 0.342 m/ka for the Little Grand Wash fault relates directly to Green River incision and agrees with previous work on the Colorado Plateau, providing a further data point for characterisation of uplift of the province. For the northern fault of the Salt Wash graben a rate of 0.168 m/ka for the tributaries running through the area gives a robust method with which to estimate ages for un-dated mounds. The results of radiometric dating and incision rate age estimation of travertine mounds shows that leakage can last for timescales of 100,000’s of years, while high resolution U-Th dating of an individual mound demonstrated that leakage from a single point can last for a minimum of ~11,000 years. A range of travertine ages show that leakage to the surface has constantly switched location through time, while the presence of three mounds of distinct age at one location demonstrate that pathways can become repeatedly re-used over periods of ~45,000 years. There is no evidence of temporal periodicity in travertine deposition but there is a distinct spatial pattern of leakage as shown by localised similarities in the initial uranium chemistries of travertine mounds. Initial leakage is proximally located to the axial trace of the Green River anticline and subsequent leakage spreads from this central point along the fault plane in both east and west directions. The switching of fluid flow pathways to the surface can be explained by three main mechanisms: mineralisation, 3-phase interference of CO2 related fluid flow and seismically triggered alteration in dynamic strain acting upon the hydrology of the faults. These mechanisms have differing influences in each area - demonstrating that the behaviour of fluid flow switching in a system confined to damage zone fractures (Little Grand Wash fault) is different to a system leaking through an unconfined aquifer (northern fault of the Salt Wash graben). Coupling of travertine ages with estimates of their volumes provided a total worse case scenario for quantity of CO2 leakage of 6.2 x 10^6 ± 1.7 x 10^6 tonnes for the Little Grand Wash fault and 7.4 x 10^6 ± 2 x 10^6 tonnes for the northern fault of the Salt Wash graben. From these totals time averaged leakage rates of 55 ± 15 and 47 ± 13 tonnes/year were estimated for each fault. The leakage rate for the actively precipitating Crystal Geyser travertine (which is the result of anthropogenic exploration drilling) is estimated to be 3,153 ± 851 tonnes/year. These total and modern rates provide analogues for leakage via caprock failure and catastrophic wellbore failure. Applying them to large scale storage sites such as Weyburn and Gorgon revealed that for caprock failure complete leakage of these reservoirs will take place over timescales of 10^5-10^6 years, while for catastrophic failure of a single well complete leakage of these reservoirs could occur over as little as 10^3 – 10^4 years. This finding has important implications for the successful monitoring of anthropogenic storage sites

Preliminary investigation on temperature, chemistry and isotopes of mine water pumped in Bytom geological basin (USCB,Southern Poland) as a potential geothermal energy source

Mine water from both operating and abandoned mines can be used for individual space heating projects, district heating/cooling systems or for preheating air for mine ventilation. Examples of such applications are already known from Canada, US, Netherlands, UK, and Spain. The Upper Silesian Coal Basin (USCB) in Poland, where 34 of 65 hard coal mines have been abandoned since 1989, represents a potentially large opportunity for mine water heating schemes. This paper describes the mines from Bytom (northern USCB) as a potential location for ground source heat extraction projects. Hydrogeological and hydrogeochemical studies of pumped waters have been carried out in order to better understand the potential of the Bytom heat resource. The monitoring program is still ongoing, but initial results compare favorably with existing mine water geothermal source systems where water temperatures are comparable or lower than those found at Bytom. Initial hydrochemical and isotope data demonstrate stability in water composition at most of the monitoring points. These data elucidate the hydrogeological cycle during active dewatering and provide a baseline for understanding the geothermal behavior of the system, which is crucial for optimizing heat extraction. Preliminary results also reveal very stable mine water temperatures in the pumped, and hydrologically connected, Szombierki system and suggest remarkable stability in the characteristics of the main hydrothermal reservoirs

QICS work package 1: migration and trapping of CO2 from a reservoir to the seabed or land surface

Natural CO2 seeps can be used as analogues for studies into surface flux and impact resulting from leaking engineered geological CO2 reservoirs. However their long-lived nature often means that the local environment has either adapted or evolvedaround the seepage site. The ‘Quantifying Impact of carbon storage’ (QICS) experiment provides the solution to this issue by releasing CO2 into an environment previously untouched by CO2. Work Package 1 (WP1) of the QICS project is primarily concerned with the migration of CO2 in the subsurface and how to relate the results of the relatively shallow experiment to a full storage scale setting in the UK North Sea. The main objectives of WP1 are to investigate potential leakage pathways from the reservoir to the surface, determine possible leakage rates and assess the potential volumes of leaked CO2 that can reach the surface environment

Assessing Potential Shale Gas Impacts on Groundwater Resources: Recommendations for Groundwater Monitoring and Definition of Baseline Conditions

Exploitation of shale gas by hydraulic fracturing (fracking) is highly controversial and concerns have been raised regarding induced risks from this extraction technique. The SHEER project, an EU Horizon 2020-funded project, is developing best practice to understand, prevent and mitigate the potential short- and long-term environmental impacts and risks of shale gas exploration and exploitation. Three major potential impacts were identified: groundwater contamination, air pollution and induced seismicity. This presentation will deal with the hydrogeological aspect. As part of the SHEER project, baseline and operational groundwater monitoring was carried out at an extraction site in Wysin, Northern Poland. Baseline monitoring was carried out from December 2015 to June 2016 in four monitoring wells intercepting the main drinking water aquifer located in Quaternary sediments. Fracking operations occurred in two deviated horizontal wells in June and July 2016. Monitoring continued for 1.5 years post-fracking although no significant gas production occurred during this period. Collected data include measurements of groundwater level, electrical conductivity and temperature at 15-min intervals, field measurements of groundwater physico-chemical parameters and frequent sampling for laboratory analyses. Groundwater samples were analysed for a range of constituents including dissolved gases and stable isotopes. This presentation will provide an overview of the monitoring results and the ensuing recommendations for groundwater monitoring in the context of shale gas exploitation. These recommendations relate to: (1) site characterisation prior to any activity, (2) baseline and on-going groundwater monitoring, and (3) relationships between regulators, operators and general public. During the presentation, we will particularly focus on the monitoring methodology and establishing accurate background values for key parameters for baseline monitoring, including suggestions on how to clearly communicate the information to the general public. We will conclude on techniques to identify deviations from baseline values

An investigation into the limitations of low temperature district heating on traditional tenement buildings in Scotland

Domestic heating accounts for 64% of domestic energy usage in the UK, yet there are currently very few viable options for low carbon residential heating. The government’s carbon plan commits to improving the uptake of district heating connections in new build dwellings, but the greatest carbon saving can be made through targeting traditional housing stock. This paper aims to quantify the potential carbon and energy savings that can be made by connecting a traditional tenement building to a district heating scheme. The study uses a transient system simulation tool (TRNSYS) model to simulate the radiator system in a tenement block and shows that a significant benefit can be achieved by reducing the supply temperature; however, the minimum supply temperature is drastically limited by the building condition. Therefore, the study also critically compares the benefits of a lower supply temperature against minor refurbishments. It was found that improving building conditions alone could offer a 30% reduction in space heating energy consumption, while building improvements and integration of a river source heat pump could offer almost a 70% reduction. It is the recommendation of this study that a dwelling be improved as much as economically possible to achieve the greatest carbon and energetic savings

Exponential Trends in Flowback Chemistry From a Hydraulically Stimulated Deep Geothermal Borehole in Granite; Pohang, South Korea

Samples of flowback water from a 4.3 km deep geothermal borehole in granite (Pohang, South Korea) were collected following a period of hydraulic stimulation by injection of surface water. Electrical conductivity, temperature and water chemistry of the flowback water were measured. To a first approximation, the data conform closely to a simple ‘mixing tank’ model, with an exponential trend between two end members: an initial injected surface water to a more brackish ‘resident groundwater’ composition. Significant deviation from the ‘mixing tank’ trend would be an indication of significant recent water-rock interaction or other anomalous factors. Such a deviation can tentatively be seen in Na+/Cl- data, especially between 88 and 200 m3 flowback (2.8 to 8.8 hr)

Geothermal Energy and Water Resources in Ethiopia

No abstract available

What Have We Learnt About CO2 Leakage in the Context of Commercial-Scale CCS?

The viability of Carbon Capture and Storage (CCS) depends on the reliable containment of injected CO2 in the subsurface. Robust and cost-effective approaches to measure monitor and verify CO2 containment are required to demonstrate that CO2 has not breached the reservoir, and to comply with CCS regulations. This includes capability to detect and quantify any potential leakage to surface. It is useful to consider the range of possible leak rates for potential CO2 leak pathways from an intended storage reservoir to surface to inform the design of effective monitoring approaches. However, in the absence of a portfolio of leakage from engineered CO2 stores we must instead learn from industrial and natural analogues, numerical models, and laboratory and field experiments that have intentionally released CO2 into the shallow subsurface to simulate a CO2 leak to surface. We collated a global dataset of measured or estimated CO2 flux (CO2 emission per unit area) and CO2 leak rate from industrial and natural analogues and field experiments. We then examined the dataset to compare emission and flux rates and seep style, and consider the measured emission rates in the context of commercial scale CCS operations. We find that natural and industrial analogues show very wide variation in the scale of CO2 emissions, and tend to be larger than leaks simulated by CO2 release experiments. For all analogue types (natural, industrial, or experiment) the emission rates show greater variation between sites than CO2 flux rates. Quantitation approaches are non-standardized, and that measuring and reporting both the CO2 flux and seep rate is rare as it remains challenging, particularly in marine environments. Finally, we observe that CO2 fluxes tend to be associated with particular emission characteristics (vent, diffuse, or water-associated). We propose that characteristics could inform the design and performance requirements for CO2 leak monitoring approaches tailored to detect specific emission styles

A combined pumping test and heat extraction/recirculation trial in an abandoned haematite ore mine shaft, Egremont, Cumbria, UK

A pumping test at rates of up to 50 L s⁻¹ was carried out in the 256 m-deep Florence Shaft of the Beckermet–Winscales–Florence haematite ore mine in Cumbria, UK, between 8th January and 25th March 2015. Drawdowns in mine water level did not exceed 4 m and the entire interconnected mine complex behaved as a single reservoir. Pumping did, however, induce drawdowns of around 1 m in the St. Bees Sandstone aquifer overlying the Carboniferous Limestone host rock. During a second phase of the pumping test, a proportion of the 11.3–12 °C mine water was directed through a heat pump, which extracted up to 103 kW heat from the water and recirculated it back to the top of the shaft. Provided that an issue with elevated arsenic concentrations (20–30 µg L⁻¹) can be resolved, the Florence mine could provide not only a valuable resource of high-quality water for industrial or even potable uses, it could also provide several hundred to several thousand kW of ground sourced heating and/or cooling, if a suitable demand can be identified. The ultimate constraint would be potential hydraulic impacts on the overlying St Bees Sandstone aquifer. The practice of recirculating thermally spent water in the Florence Shaft produced only a rather modest additional thermal benefit